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Once the mejais is done, hello to killing spree! The build allows for slightly better durability, tons of AP damage, magic penetration to burst down a champion and a bit of Magic Resistence for early mid.
Then one point in W to trigger the silence and to chase/escape.
After that I put another point in Q and one in E to have my basic combo ready.
Another point in Q at level 5 and at level 6 get your ulti.
Then max out R(whenever possible) then Q, then max W and lastly E.
Early game combo is Q + W and repeat as it silences the enemy.
The Combo for Leblanc that I use is E + Q + W + W when i harass mid-game
The combo to burst down a champion completely during later game is E + Q + W + 3 moving basic attacks + Q + R
That combo with max mejai's stack and rod of ages should take out the enemy caster/carry.
This gives you the early BAM to your Q + W combo when your harassing. In early game, the flat ability power will allow you to burst down a champion and get stacks on Mejais. Late game, when the enemy has Magic Resist, the Mag Pen marks will come into play as it ignores some defence and allows you to damage just as well. I try to focus on getting as much damage as possible to get the upper hand in a 1v1 fight(as Leblancs combo targets 1 champion at a time).