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Volibear Build Guide by Kenste
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Philosopher's Stone: Rush this right away, and keep it until you're final item frozen heart. the coin stack really adds up and the hp and mana regen will benefit you through out the game.
Mercury's treads: Important item for Volibear, the speed and the magic resist with the tenacity so you can really reduce any incoming stuns silences slows. etc.
Warmogs: For the health, great stamina in team fights.
Aegis of the legion: For the health, armor and magic resist, the passive also benefits you're team during team fights.
Thornmail: For the great armor and passive so you can't be focused, and if they do they will be heavily punished.
Force of Nature: For the great magic resist, and health regeneration also the movement speed helps a lot with rolling thunder to ensure you're enemy's do not escape.
Frozen Heart: provides great armor and extra mana and at the same time reducing all attack speeds on the other team by 20% which is great for team fights.