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1) Rylai's: sion's only magic damage comes from his stun (which has the same length as the slow on rylai's), and an AoE nuke than can be cancelled by in 1-2 seconds by any AD carry
2) Lack of Lich Bane: without lich Bane (about) half of your burst damage can be easily eliminated, while with lich bane you can increase your burst damage by about 50%, or, if you time it right you can even double it (although this requires you wait 2 seconds between abilities, which may not always be a good idea). Lich Bane also gives an additional 350 mana, 80 AP, and 7% movespeed
also, when it comes to dealing with AP Sions's mana problems, keep in mind that he is the AP nuke, and therefore should grab blue buff whenever possible, except early on when the jungler gets it
Regarding your 3 builts:
(I consider 2nd as fun build.)
You should never grab RoA/Rylai's or Archangel's.
-Sion and Chogath should be the only caster who can stack HP without item dependence. Dont waste money on HP if you can grab resistance items (which you need thx to bubble range and its shield synergising with Ar/MR.
-You dont need an extra Mana boost from RoA or Archangel's. Runes, maybe Masteries and Morello's or DFG are enough.
- That slow on Rylai's... neither can you maintain it effectively nor do you want to stick close to s1 who you cant finish off within the next 2-3 blows.
- Lich Bane. Total personal playstyle, wont hold it against you. IMO an early Sheen is great for laning and will give you more than enough skill spam freedom. And late game youre close enough to land Lich Bane anyways.
If you NEED Mana from Tear/Catalyst early while using Greater Seal of Replenishment, youre doing sth wrong IMO.
Skill order:
Enrage earlier, latest lvl 3: You talk about farming yourself, do it then.
Cannibalism: You dont go for spell vamp, so its GREAT to reg after every fight (you wont need it while facing enemy champs 80% of time ofc) early to late only Enrage needed + 1 minion wave.
How does one actually BEAT Sion in a lane? Casters waste a LOT of mana trying to go through Sion's shield, only for him to lose 0hp, while most AD melees cannot trade without Sion coming out in one way. Tried out Sion for 2 games in ranked and quite a few times in normals, but it just feels like Sion is extremely hard to beat in lane. How does one counter Sion?
You need a good CC team with a good AD Carry with nice damage :) Or just avoid his shield explode and after that put all your CCs on him and finish him.