Yeah you would probably get more help from twitch themselves, but you can keep this here in the offchance someone sees it and knows the solution. I would suggest asking twitch though and not waiting for us. ;P
Thanks to GrandMasterD for my sig!
We may have hit some technical limits with Twitch. I've done some work to harden the polling script, it seems to have gotten over that hurdle. Try again, and make sure you give it a good 10-15 minutes as MOBAFire can take that long to poll and update your stream. If it still doesn't work then, let me know!
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twitch.tv/allnightlong22