If you're going solely by win rates:
Urgot (42.7%),
Twitch (44.84%),
Vayne (46.84%),
Ezreal (47.49%),
Lucian (48.82%) and
Quinn (49.38%). Everything else is either above 50% or very very slightly under.
Win rates alone aren't really a great indicator though, for example Lucian and
Miss Fortune's (53.4%) make no sense whatsoever to me. There's a lot of external factors that can influence them - for instance people who've never played ADC in their life and get forced into the role might be more likely to go for Lucian because he's considered easy/OP and drag down his win rate. Or people might just not be updating to his new item builds.
fk the haters tho ezreals the best






Win rates alone aren't really a great indicator though, for example Lucian and

fk the haters tho ezreals the best
Jarvan is the best ad-carry.
Ty MM and Blood for the sigs :3 | Rammus is comming back - heard it here first!

"Carrying"-guide | My reviewservice

"Carrying"-guide | My reviewservice
ashe..
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Still it didn't make much of an impact.
Then
Quinn shall be an adc cuz she got played....once..
Both champions were designed to be ADC's either way. Also, Yellowpete plays a pretty good Urgot (of course nothing impressive because urgot is a sucky champ but still ... )