I would like to ask you something regarding the On Hit TF build.What do you think about buying Tiamat as a first major item?

Glad I could help out

Hmm, that is interesting, I've been told that a few times, but I've never actually seen it, but they are similar in the idea of showing 5 tf builds.
Anyway, to answer the 1st question, I get the starting gold because I generally get a potion also, but I didn't think to put it into the build guide, so I fixed that. I do that so that I get that extra survivability and damage from the ring as well as a clutch pot in case of something like minion damage or Ignite.
2nd Question: It's a preference, but I would advise taking the 9/0/21 just because overall, my build doesn't offer a lot of cooldown reduction, but it does offer a lot of damage, so the metagame helps round out everything. The other reason, is because if I were to take 21/0/9, than in a duel against a champion with full health and I have full health, I can expect somewhere around a bonus 24-40 AP from my mastery setup, which overall translates to an extra 26 points or so on Wild Cards. But with the 9/0/21 setup, I have gold card up more often for CC, Destiny up more often to check the other team, and more wild card spam.
3rd Question: I get 6 health potions. I explain it later in the guide, but I'll go ahead and put them all in so that it's easier to find.

Nice guide i like a lot the hibrid and the AS build, i was thinking to try an hybrid build so tnx for giving me the base :D

Nice guide, remembers me of an old Twisted Fate guide some time ago. "Doin' it [100% of fate]"
http://www.mobafire.com/league-of-legends/build/twisted-fate-doin-it-100-of-fate-62698

But that one got expired, and this one is new. ^^

Anyways, I have 3 questions:
1. Why the extra starting gold mastery on AP TF? You only buy doran's ring.

2. Why 9/0/21 on AP TF? Why not 21/0/9?

3. You only buy 1 health pot as jungler, or all health pots? 'Cause your item build only shows one.

Glad you liked it!

Awesome guide man, I really loved the On-Hit build. That thing does wonders in 1v1 and against tanky champions. Keep up the good work!

Sweet man glad I could help. Congrats on the awesome games!

Nice guide, I went looking for one for a jungling TF after I heard it was possible, this covers all the bases well and made ganking with destiny the ridiculous amount of fun it used to be before the nerf :)

Thanks 8)

I really love the on hit TF! Best!

Thanks for the catch, I didn't ever account from the CDR passive on Stacked Deck. I'll go in and fix that. While it is true that the cooldown in the beginning of the game is nice, it isn't really a mandatory part of my build that I bank heavily on, I would much rather have some power to back up my attacks than be repetitive. Thanks for the compliment, it's the little stuff like that that keeps me going.
p.s. I like your sig 8)