Take some time checking out some guides here just like FalseoGod said. Anyways if you want simple runes and masteries
Ashe and Master Yi:
Masteries
Ashe 21-9-0
Master Yi 21-9-0 or 21-0-9 (you take 21-0-9 if you're jungling)
Maokai 9-21-0 if your laning (you take (0-21-9 if you're jungling which is where you should be)
Runes
Ashe: take +15 AD, 13 armor, 12 MR ( all tier 3 runes)
Master yi: you can take the same as ashe, but you can also swap around some with attack speed but I really don't like master yi overall)
Maokai: take movement speed quints, flat mr or scaling mr, flat armor
Btw Maokai is best build with slight AP. Sample build which I really like to use
Mobility Boots
Shurelya's Battlesong
Frozen Heart or Iceborn Gauntlet
Rylai's Crystal Scepter
Abyssal Mask
Runic Bulwark
Ashe and Master Yi:
Masteries
Ashe 21-9-0
Master Yi 21-9-0 or 21-0-9 (you take 21-0-9 if you're jungling)
Maokai 9-21-0 if your laning (you take (0-21-9 if you're jungling which is where you should be)
Runes
Ashe: take +15 AD, 13 armor, 12 MR ( all tier 3 runes)
Master yi: you can take the same as ashe, but you can also swap around some with attack speed but I really don't like master yi overall)
Maokai: take movement speed quints, flat mr or scaling mr, flat armor
Btw Maokai is best build with slight AP. Sample build which I really like to use
Mobility Boots
Shurelya's Battlesong
Frozen Heart or Iceborn Gauntlet
Rylai's Crystal Scepter
Abyssal Mask
Runic Bulwark
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tnx Maokai for very very Health and Ability !