You can't get two sheen procs off of one WQ combo. You might be able to thread in an extra autoattack's worth of damage, but the delay between the spells isn't long enough for sheen to cool down.

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Returning to the game after a very long time off, leveling an account to 30, and been playing some "just for fun stuff" while I level up, including AP Alistar (next Bjergsen NA here). I'm curious about the mechanics of ensuring that you get the sheen proc auto attack after your W as well as Q.
If anyone can describe how they have success doing it, I seem to be struggling with it. Generally I just try to W, and mid "charge" right click the target, then try to Q. It seems like a good bit of the time, I either pulverize before auto attacking, OR the headbutt goes through, and I miss my Q. Is this the general trick to doing it, and it just takes a lot of practice? (My ping isn't SUPER, but it's pretty low, so I don't think its totally a ping problem).
Or if anyone has a way of helping me master this combo, would appreciate it! Thanks in advance!