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Sion by Poney Power
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I start with a Doran's Ring to get a little bit of Ability power,health & mana regen.
After I bought 2 Health Potion because we never know when they can save you...
Depends on what I need, I bought Boots of Speed for more speed or a Sapphire Crystal for more mana.
After I need to finish my boots to get Sorcerer's Shoes to get more movement speed & more magic penetration.
One of te things I think you most need its Sheen because with the passive your second spell will deal 100% more damage (so double damage) So I usually Does my Shield,Stun the target & than explode my shield...If you do your shield after stun the target you may not have the chance to explode it...
To get a little bit less squishy I bought a Warmog's Armor.
After I bought a Rabadon's Deathcap to get lot of more Ability power.
The 2 last items are very good but you can also take a lot of other stuff...
I take a Nashor's Tooth to get more attack speed,more ability power & more cooldown reduction.I think its a good item because Sion can do a lot of damage with his "E" (Enrage) who gives him more attack damage but cost health but Aniway you got a Warmog's Armor so you don't care if you loose 16hp when you attack cause you regain it.
I also take a Guinsoo's Rageblade to get more damage,more ability power & more attack speed with the passive of this item you may kill someone really quick ;)