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Another Quinn combo is fairly unique that most players don't really know about! it's;
(Passive)than, wait till harrier is 1 second away from cooling down+(Passive)+E+(Passive)+Q
That is a great way to get last second harrass as the ADC Quinn, Considering most ADC's would think that your Harrier is on cooldown, but popping the passive last second will refresh instantly!
Valor doesn't really have a combo it's more of an all in type of technique to secure the kills, and killing the backline faster.
But here is valor's Combo
(Valor)+E+R(AT THE SAME TIME)+(PASSIVE)+Q = That should do alot more damage, because Quinn's ulimate AOE.
For that combo I strongly recommend to smartcast your "E", making it a ton more easier to burst with your R+E+R+Q <--- that is the combo.
Con's: If Quinn doesn't really get Fed, she can't really provide the team with alot of burst when needed. That is why it's best to play Quinn against someone she counters and not someone that counters her. Here are some people that I consider pretty solid counters for Quinn.
*Graves(1): Do NOT, Play Quinn if you're against this champion. This guy is meant to destroy you.He can just Q+R and you're dead. His Wave clear is alot more stronger. He could outfarm you better. His passive makes you do alot less damage. Only play Quinn if you're positive you could beat him.
*Lucian(2): Lucian is a lane bully, however he has 500 range. Yet his E+Passive is completely broken in terms of harrass. Example, Lucian Q+Passive+W+Passive+E+Passive does as much damage as Quinn's R+E+R+Q combo. Not only that He could dodge your Q combo. and out trade you when you try to (Passive)+E+(Passive)+Q, that combo is as equal to Lucian's Q+Passive+W+Passive. Play Quinn only if you think you could survive in lane with him, or if you believe your support is skilled enough to zone him in lane.
*Caitlyn(3): Boy oh Boy, this champion is annoying. 600+ Range Level 1, where as you have 525, however cait isn't made to fight head on, she isn't a duelist. If you could pull your combo's off on her you could easily win lane, but beware! If she could zone you, your lane could be lost.
*Corki(4): Corki's True damage+Q burst+E armor pen+Consistent Ult's= Dead quinn. Do not pick Quinn against him unless you kill him 5 times before 10 minutes of the game.
*Varus(5): Far more bursty than Quinn, Could ult her and kill her when she tried to R to him.
*Ezreal(6): If played correctly, a good Ezreal could nail a Quinn just by keeping his distance and Q. He could dodge her Q with his E and still provide harrass.