Rell Build Guide by HVfun
[10.25.] Rell Jungle - Horsin’ Around
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+10% Attack Speed
+9 Adaptive (5.4 AD or 9 AP)
Champion Build Guide
Anyways, read on and I'll give you some tips on how to play her in the jungle.
If you can't get a good angle on the target and walk up behind them, you can try to start the gank with W and then E to stun, but you'll usually be too slow to finish the kill.
Your ult isn't that complicated to use. You usually want to use it to draw targets into your team's damage, but you can also use it to bait and peel. For example, sometimes it's best to let the fight draw out a little bit, and then use your ult when one of your teammates is at about 25% health and take the opponent away from them. I'm still getting used to this ult, and I'll try to update if I figure out some more tricks.